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    State-of-the art of the regulations and requirements to access a doctoral programme in each participant country (M29). Report summarising all the information collected from academic partners regarding the requirements to access a doctoral programme in each institution and the regulation under which the doctoral programme of the respective country is governed. It will also explain the approach based on co-tutelles, giving the total number of planned agreements.

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    Authors: Yana Galazutdinova; Mario Grágeda; Luisa F. Cabeza; Svetlana Ushak;

    In this study, an inorganic mixture based on bischofite (industrial by‐product) was developed and characterized for its application as a phase change material for low‐temperature thermal energy storage. The most appropriate composition was established as 40 wt% bischofite and 60 wt% Mg(NO3)2 · 6H2O. Thermophysical properties were defined and compared with those of the mixture with synthetic MgCl2 · 6H2O. The heat of fusion and melting temperature were measured as 62.0°C and 132.5 kJ kg−1 for the mixture with MgCl2 · 6H2O and 58.2°C and 116.9 kJ kg−1 for the mixture with bischofite. The specific heat capacity values, cycling, and thermal stability for both mixtures were also determined. For the mixture with MgCl2 · 6H2O, the densities of the solid and liquid states were 1517 kg m−3 (ambient temperature) and 1515 kg m−3 (at 60‐70°C), respectively. For the mixture with bischofite, the densities of the solid and liquid states were 1525 kg m−3 (ambient temperature) and 1535 kg m−3 (at 60‐70°C), respectively. Both mixtures show supercooling of about 23.4 and 34.1°C for the mixture with bischofite and MgCl2 · 6H2O, respectively. In addition, it was shown that supercooling may be reduced by increasing the quantity of material tested. Thereby, it was established that an inorganic mixture based on bischofite is a promising PCM for low‐temperature thermal energy storage applications. Funding informationComisión Nacional de InvestigaciónCientífica y Tecnológica, Grant/AwardNumber: CONICYT/FONDAP 15110019,CONICYT‐PCHA/Doctorado Nacional paraEstudiantes Extranjeros 2014/Folio63140052, ERANet‐LAC 2nd Joint Call,ERANET‐LAC 2015‐2016, projectELAC2015/T06‐0988; FONDECYT, Grant/Award Number: 1170675; Spanish Govern-ment, Grant/Award Number: ENE2015‐64117‐C5‐1‐R (MINECO/FEDER); CatalanGovernment, Grant/Award Number: GREA(2014 SGR 123); European CommissionSeventh Framework Programme, Grant/Award Number: PIRSES‐GA‐2013‐610692(INNOSTORAGE); European Union0s Hori-zon, Grant/Award Number: 657466(INPATH‐TES)

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    Report on the workshop carried out for all intended educational providers inside the project

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    Authors: Badenhorst, Heinrich; Cabeza, Luisa F.;

    Energy storage is a key challenge to a sustainable energy supply. To design new storage systems accurateand representative thermal property measurements are essential. The T-history method is quick anduncomplicated, however numerous adaptations have been proposed over the years. In this study thesemethods have been classified and critically assessed based on their mathematical formulation and exper-imental configuration. They can be broadly categorized according to one of three assumptions regardingthe heat transfer coefficient for natural convection: it is constant either as a function of time or tem-perature, or it is negligible. This work proves in addition that the heat transfer coefficient for naturalconvection, varies both as a function of time and temperature. This is demonstrated both experimentallyand through rigorous simulation of the proposed configurations. Thus T-history methods which show themost promise for precise and unambiguous measurements eliminate convection by making conductionthe dominant thermal resistance in the system. These techniques can be tailored to different materialsand do not require a simultaneous reference due to the use of a rigorous fundamental model comparedto the lumped parameter approximation. The addition of heat flux sensors to quantify actual heat lossesis recommended for absolute measurement certainty. The research leading to these results has received funding from the European Commission Seventh Framework Programme (FP/2007-2013) and under Grant agreement N°PIRSES-GA-2013-610692 (INNOSTORAGE), and from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 657466 (INPATH-TES). The work is partially funded by the Spanish government (ENE2015-64117-C5-1-R (MINECO/FEDER)). Dr. Luisa F. Cabeza would like to thank the Catalan Government for the quality accreditation given to the research group GREA (2014 SGR 123).

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    Thermochimica Acta
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    Repositori Obert UdL
    Article . 2017
    License: CC BY NC ND
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    Thermochimica Acta
    Other literature type . Article . 2017 . Peer-reviewed
    License: Elsevier TDM
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      Thermochimica Acta
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      Article . 2017
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      Thermochimica Acta
      Other literature type . Article . 2017 . Peer-reviewed
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    Authors: Paksoy, Halime; Kardas, G.; Konuklu, Yeliz; Cellat, Kemal; +1 Authors

    Phase change materials (PCM) can be used in passive building applications to achieve near zero energy building goals. For this purpose PCM can be added in building structures and materials in different forms. Direct incorporation, form stabilization and microencapsulation are different forms used for PCM integration in building materials. In addition to thermal properties of PCM itself, there are several other criteria that need to be fulfilled for the PCM enhanced building materials. Mechanical properties, corrosive effects, morphology and thermal buffering have to be determined for reliable and long-Term applications in buildings. This paper aims to give an overview of characterization methods used to determine these properties in PCM added fresh concrete mixes. Thermal, compressive strength, corrosion, and microscopic test results for concrete mixes with PCM are discussed. © Published under licence by IOP Publishing Ltd. The authors would like to acknowledge the funding provided by the European Union’s Horizon 2020 research and innovation programme under grant agreement No 657466 (INPATH-TES). 3rd International Conference on Innovative Materials, Structures and Technologies, IMST 2017 --27 September 2017 through 29 September 2017 -- -- 657466

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    Çukurova University Institutional Repository
    Other literature type . Article . Conference object . 2019 . 2017 . Peer-reviewed
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    Article . 2017
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    IOP Conference Series : Materials Science and Engineering
    Article . 2017 . Peer-reviewed
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      Çukurova University Institutional Repository
      Other literature type . Article . Conference object . 2019 . 2017 . Peer-reviewed
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      IOP Conference Series : Materials Science and Engineering
      Article . 2017 . Peer-reviewed
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    Authors: Coma, Julià; de Gracia, Alvaro; Chàfer, Marta; Pérez, Gabriel; +1 Authors

    Extensive green roofs have been consolidated as good tools for passive energy saving systems in buildings,providing a more sustainable trend in the building field. However, as the growth of vegetation is variable depending on external factors such as weather conditions, disease, etc. the coverage of plants cannot ensure uniformity and consequently the 'shadow effect' cannot be considered as a constant parameter.On the other hand, materials used in substrate and drainage layers should provide a constant 'insulation effect' depending only on their physical properties and water content. In spite of this, the complexity of disaggregated materials used in internal layers of extensive green roofs implies a lack of real data about their thermal properties. The main objective of this study is to determine experimentally the physical properties of different disaggregated materials from the internal layers of extensive green roofs commonly used in Mediterranean climates. The experimentation presented in this paper allows to calculate the thermal transmittance in steady-state (U-value), the heat storage capacity (Cp), and the dynamic thermal response under a daily thermal oscillation. This work was partially funded by the Spanish government (ENE2015-64117-C5-1-R (MINECO/FEDER) and ULLE10-4E-1305), in collaboration with the company Buresinnova S.A (C/Roc Boronat 117-125, baixos 08018 Barcelona). Moreover, the research leading to these results has received funding from the European Union's Seventh Framework Programme (FP7/2007-2013) under grant agreement n° PIRSES-GA-2013-610692 (INNOSTORAGE) and from European Union’s Horizon 2020 research and innovation programme under grant agreement N° 657466 (INPATH-TES). The authors would like to thank the Catalan Government for the quality accreditation given to their research group (2014 SGR 123). Alvaro de Gracia would like to thank Ministerio de Economia y Competitividad de España for Grant Juan de la Cierva, FJCI-2014-19940. Finally, Julià Coma wants to thank the Departament d'Universitats, Recerca i Societat de la Informació de la Generalitat de;1; Catalunya for his research fellowship.

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    Energy and Buildings
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    Repositori Obert UdL
    Article . 2017
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      Repositori Obert UdL
      Article . 2017
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    Authors: Anabel Palacios; Alvaro de Gracia; Laia Haurie; Luisa F. Cabeza; +2 Authors

    The implementation of organic phase change materials (PCMs) in several applications such as heating and cooling or building comfort is an important target in thermal energy storage (TES). However, one of the major drawbacks of organic PCMs implementation is flammability. The addition of flame retardants to PCMs or shape-stabilized PCMs is one of the approaches to address this problem and improve their final deployment in the building material sector. In this study, the most common organic PCM, Paraffin RT-21, and fatty acids mixtures of capric acid (CA), myristic acid (MA), and palmitic acid (PA) in bulk, were tested to improve their fire reaction. Several flame retardants, such as ammonium phosphate, melamine phosphate, hydromagnesite, magnesium hydroxide, and aluminum hydroxide, were tested. The properties of the improved PCM with flame retardants were characterized by thermogravimetric analyses (TGA), the dripping test, and differential scanning calorimetry (DSC). The results for the dripping test show that fire retardancy was considerably enhanced by the addition of hydromagnesite (50 wt %) and magnesium hydroxide (50 wt %) in fatty acids mixtures. This will help the final implementation of these enhanced PCMs in building sector. The influence of the addition of flame retardants on the melting enthalpy and temperatures of PCMs has been evaluated. Peer Reviewed

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    Recolector de Ciencia Abierta, RECOLECTA
    Other literature type . Article . 2018 . Peer-reviewed
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    Repositori Obert UdL
    Article . 2018
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      Recolector de Ciencia Abierta, RECOLECTA
      Other literature type . Article . 2018 . Peer-reviewed
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      Repositori Obert UdL
      Article . 2018
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    Authors: PISELLO, ANNA LAURA; FABIANI, CLAUDIA; MAKAREMI, NASTARAN; CASTALDO, VERONICA LUCIA; +4 Authors

    There is considerable interest recently in by-products for application in green buildings. These materials are widely used as building envelope insulators or blocks. In this study, an experimental study was conducted to test stranded driftwood residues as raw material for possible thermo-acoustic insulation panel and environmentally sustainable brick. The thermal and acoustic characteristics of such a natural by-product were examined. Part of samples were mineralized by means of cement-based additive to reinforce the material and enhance its durability as well as fire resistance. Several mixtures with different sizes of ground wood chips and different quantities of cement were investigated. The thermo-acoustic in-lab characterization was aimed at investigating the thermal conductivity, thermal diffusivity, volumetric specific heat, and acoustic transmission loss. All samples were tested before and after mineralization. Results from this study indicate that it is possible to use stranded driftwood residues as building materials with competitive thermo-acoustic properties. In fact, the thermal conductivity was shown to be always around 0.07 W/mK in the unbound samples, and around double that value for the mineralized samples, which present a much higher volumetric specific heat (1.6 MJ/m3K) and transmission loss capability. The lignin powder showed a sort of intermediate behavior between the unbound and the mineralized samples. The authors would like to thank Gabriele Franceschetti and CVR s.r.l. for assisting the mineralization procedure of the samples. Anna Laura Pisello’s acknowledgments are due to the “CIRIAF program for UNESCO” in the framework of the UNESCO Chair “Water Resources Management and Culture”, for supporting her research. The research was founded by the Italian Environmental Ministry with an agreement entitled “Recovery and energy valorization of stranded driftwood residues” in 2014–2016. The research team leading to these results has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No. 657466 (INPATH–TES) and No. 678407 (ZERO-PLUS).

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    Energies
    Other literature type . Article . 2016 . Peer-reviewed
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    Authors: Pau Gallart-Sirvent; Marc Martín; Gemma Villorbina; Mercè Balcells; +4 Authors

    GREA and DBA are certified agents TECNIO in the category of technology developers from the Government of Catalonia. We thanks to Subproductos Cárnicos Echevarria y Asociados S.L (Cervera, Spain) for supplying the non-edible fat. Moreover, the research leading to these results has received funding from the European Commission Seventh Framework Programme (FP/2007–2013) under grant agreement no. PIRSES-GA-2013-610692 (INNOSTORAGE) and from the European Union's Horizon 2020 research and innovation program under grant agreement no. 657466 (INPATH-TES). The authors would like to thank the Catalan Government for the quality accreditation given to their research groups GREA (2014 SGR 123), Agricultural Biotechnology Research Group (2014 SGR 1296) and DIOPMA (2014 SGR 1543). This work has been partially funded by the Spanish government (CTQ2015-70982-C3-1-R (MINECO/FEDER), ENE2015-64117-C5-1-R (MINECO/FEDER) and ENE2015-64117-C5-2-R (MINECO/FEDER)). Dr Camila Barreneche would like to thank Ministerio de Economia y Competitividad de España for her grant Juan de la Cierva FJCI-2014-22886. Aran Solé would like to thank Ministerio de Economía y Competitividad de España for Grant Juan de la Cierva, FJCI-2015-25741. A set of compounds from non-edible fat waste was prepared and their thermal behavior was studied. The fat was hydrolyzed and crystallized in a simple and robust process to yield palmitic acid-stearic acid (PA-SA) mixtures. The PA-SA mass ratios determined by GC-FID (gas chromatography-flame ionization detection) were similar to those reported for eutectic mixtures of PCMs (phase change materials). DSC (differential scanning calorimetry) results indicated that the melting and solidification temperatures were around 55 °C and 52 °C and the latent heat of the crystallized fractions measured was around 180 kJ kg−1. The thermal cycling reliability of the eutectic mixtures was also tested during 1000 melting/freezing cycles. The loss in melting and solidification enthalpies was below 14% in all mixtures showing a promising behavior for PCM applications. Additionally, the unsaturated fatty acids were recovered and transformed to threo-9,10-dihydroxystearic acid (DHSA) and some of their inorganic salts, which were analyzed by FT-IR (Fourier transform-infrared spectroscopy) and tested for the first time using the DSC technique.

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    Authors: Rathgeber, Christoph; Schmit, Henri; Miró, Laia; Cabeza, Luisa F.; +3 Authors

    The work of ZAE Bayern was part of the project EnFoVerM and was supported by the German Federal Ministry for Economic Affairs and Energy under the project code 0327851D. The work at the University of Lleida is partially funded by the Spanish government (ENE2011-22722, ENE2015-64117-C5-1-R (MINECO/FEDER) and ULLE10-4E-1305). The authors would like to thank the Catalan Government for the quality accreditation given to their research group GREA (2014 SGR 123). GREA is a certified agent TECNIO in the category of technology developers from the Government of Catalonia. The research leading to these results has received funding from the European Union's Seventh Framework Programme (FP7/2007-2013) under grant agreement n° PIRSES-GA-2013-610692 (INNOSTORAGE) and from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 657466 (INPATH-TES). The authors want also to thank the collaboration of Antoni Gil from Massachusetts Institute of Technology (USA), Eduard Oró from Catalonia Institute for Energy Research (Spain), and Jaume Gasia and Gerard Peiró from University of Lleida (Spain). Laia Miró would like to thank the Spanish Government for her research fellowship (BES-2012-051861). The work of the University of Antofagasta was supported by FONDAP SERC-Chile (grant N° 15110019), and the Education Ministry of Chile Grant PMI ANT 1201. Authors thank the SALMAG Company for providing of bischofite. Andrea Gutierrez would like to acknowledge to the Ministry of Education of Chile her doctorate scholarship ANT 1106 and CONICYT/PAI N° 7813110010. Phase change materials (PCM) can provide high thermal energy storage capacities in narrow temperature ranges around their phase change temperature. The expectable maximum storage capacity of a PCM in a defined temperature range is equal to the enthalpy change in that range and can be determined via calorimetric measurements such as differential scanning calorimetry (DSC) or T-History calorimetry. T-History samples (aprox. 15 ml) are about 1000 times larger than DSC samples (aprox. 15 ml). Experiments in a pilot plant are performed to study the charging and discharging behaviour of even larger amounts of the PCM (aprox. 150 l). The common practise is to investigate PCM at one scale, rarely at two scales. In this work, the characterisation was carried out at three scales (DSC, T-History, and pilot plant) for four PCM (RT58, bischofite, D-mannitol, and hydroquinone). Thereby, the question arises how the enthalpy changes measured at different scales and under different conditions can be compared. In literature, the melting enthalpy is usually assigned to a single temperature without indicating the temperature range considered for evaluation. In very few instances, the enthalpy change within a defined temperature range is stated. In both cases, results measured under different conditions are difficult to compare. In this work, it is demonstrated that enthalpy-temperature plots facilitate the comparison and interpretation of measurements obtained under different experimental methods at different sample scales.

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    Article . 2018
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    Journal of Energy Storage
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    License: Elsevier TDM
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    State-of-the art of the regulations and requirements to access a doctoral programme in each participant country (M29). Report summarising all the information collected from academic partners regarding the requirements to access a doctoral programme in each institution and the regulation under which the doctoral programme of the respective country is governed. It will also explain the approach based on co-tutelles, giving the total number of planned agreements.

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    Authors: Yana Galazutdinova; Mario Grágeda; Luisa F. Cabeza; Svetlana Ushak;

    In this study, an inorganic mixture based on bischofite (industrial by‐product) was developed and characterized for its application as a phase change material for low‐temperature thermal energy storage. The most appropriate composition was established as 40 wt% bischofite and 60 wt% Mg(NO3)2 · 6H2O. Thermophysical properties were defined and compared with those of the mixture with synthetic MgCl2 · 6H2O. The heat of fusion and melting temperature were measured as 62.0°C and 132.5 kJ kg−1 for the mixture with MgCl2 · 6H2O and 58.2°C and 116.9 kJ kg−1 for the mixture with bischofite. The specific heat capacity values, cycling, and thermal stability for both mixtures were also determined. For the mixture with MgCl2 · 6H2O, the densities of the solid and liquid states were 1517 kg m−3 (ambient temperature) and 1515 kg m−3 (at 60‐70°C), respectively. For the mixture with bischofite, the densities of the solid and liquid states were 1525 kg m−3 (ambient temperature) and 1535 kg m−3 (at 60‐70°C), respectively. Both mixtures show supercooling of about 23.4 and 34.1°C for the mixture with bischofite and MgCl2 · 6H2O, respectively. In addition, it was shown that supercooling may be reduced by increasing the quantity of material tested. Thereby, it was established that an inorganic mixture based on bischofite is a promising PCM for low‐temperature thermal energy storage applications. Funding informationComisión Nacional de InvestigaciónCientífica y Tecnológica, Grant/AwardNumber: CONICYT/FONDAP 15110019,CONICYT‐PCHA/Doctorado Nacional paraEstudiantes Extranjeros 2014/Folio63140052, ERANet‐LAC 2nd Joint Call,ERANET‐LAC 2015‐2016, projectELAC2015/T06‐0988; FONDECYT, Grant/Award Number: 1170675; Spanish Govern-ment, Grant/Award Number: ENE2015‐64117‐C5‐1‐R (MINECO/FEDER); CatalanGovernment, Grant/Award Number: GREA(2014 SGR 123); European CommissionSeventh Framework Programme, Grant/Award Number: PIRSES‐GA‐2013‐610692(INNOSTORAGE); European Union0s Hori-zon, Grant/Award Number: 657466(INPATH‐TES)

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    Report on the workshop carried out for all intended educational providers inside the project

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    Authors: Badenhorst, Heinrich; Cabeza, Luisa F.;

    Energy storage is a key challenge to a sustainable energy supply. To design new storage systems accurateand representative thermal property measurements are essential. The T-history method is quick anduncomplicated, however numerous adaptations have been proposed over the years. In this study thesemethods have been classified and critically assessed based on their mathematical formulation and exper-imental configuration. They can be broadly categorized according to one of three assumptions regardingthe heat transfer coefficient for natural convection: it is constant either as a function of time or tem-perature, or it is negligible. This work proves in addition that the heat transfer coefficient for naturalconvection, varies both as a function of time and temperature. This is demonstrated both experimentallyand through rigorous simulation of the proposed configurations. Thus T-history methods which show themost promise for precise and unambiguous measurements eliminate convection by making conductionthe dominant thermal resistance in the system. These techniques can be tailored to different materialsand do not require a simultaneous reference due to the use of a rigorous fundamental model comparedto the lumped parameter approximation. The addition of heat flux sensors to quantify actual heat lossesis recommended for absolute measurement certainty. The research leading to these results has received funding from the European Commission Seventh Framework Programme (FP/2007-2013) and under Grant agreement N°PIRSES-GA-2013-610692 (INNOSTORAGE), and from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 657466 (INPATH-TES). The work is partially funded by the Spanish government (ENE2015-64117-C5-1-R (MINECO/FEDER)). Dr. Luisa F. Cabeza would like to thank the Catalan Government for the quality accreditation given to the research group GREA (2014 SGR 123).

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    Thermochimica Acta
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    Repositori Obert UdL
    Article . 2017
    License: CC BY NC ND
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    Thermochimica Acta
    Other literature type . Article . 2017 . Peer-reviewed
    License: Elsevier TDM
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      Thermochimica Acta
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      Repositori Obert UdL
      Article . 2017
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      Thermochimica Acta
      Other literature type . Article . 2017 . Peer-reviewed
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    Authors: Paksoy, Halime; Kardas, G.; Konuklu, Yeliz; Cellat, Kemal; +1 Authors

    Phase change materials (PCM) can be used in passive building applications to achieve near zero energy building goals. For this purpose PCM can be added in building structures and materials in different forms. Direct incorporation, form stabilization and microencapsulation are different forms used for PCM integration in building materials. In addition to thermal properties of PCM itself, there are several other criteria that need to be fulfilled for the PCM enhanced building materials. Mechanical properties, corrosive effects, morphology and thermal buffering have to be determined for reliable and long-Term applications in buildings. This paper aims to give an overview of characterization methods used to determine these properties in PCM added fresh concrete mixes. Thermal, compressive strength, corrosion, and microscopic test results for concrete mixes with PCM are discussed. © Published under licence by IOP Publishing Ltd. The authors would like to acknowledge the funding provided by the European Union’s Horizon 2020 research and innovation programme under grant agreement No 657466 (INPATH-TES). 3rd International Conference on Innovative Materials, Structures and Technologies, IMST 2017 --27 September 2017 through 29 September 2017 -- -- 657466

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    Çukurova University Institutional Repository
    Other literature type . Article . Conference object . 2019 . 2017 . Peer-reviewed
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    Repositori Obert UdL
    Article . 2017
    License: CC BY
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    IOP Conference Series : Materials Science and Engineering
    Article . 2017 . Peer-reviewed
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      Çukurova University Institutional Repository
      Other literature type . Article . Conference object . 2019 . 2017 . Peer-reviewed
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      Repositori Obert UdL
      Article . 2017
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      IOP Conference Series : Materials Science and Engineering
      Article . 2017 . Peer-reviewed
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    Authors: Coma, Julià; de Gracia, Alvaro; Chàfer, Marta; Pérez, Gabriel; +1 Authors

    Extensive green roofs have been consolidated as good tools for passive energy saving systems in buildings,providing a more sustainable trend in the building field. However, as the growth of vegetation is variable depending on external factors such as weather conditions, disease, etc. the coverage of plants cannot ensure uniformity and consequently the 'shadow effect' cannot be considered as a constant parameter.On the other hand, materials used in substrate and drainage layers should provide a constant 'insulation effect' depending only on their physical properties and water content. In spite of this, the complexity of disaggregated materials used in internal layers of extensive green roofs implies a lack of real data about their thermal properties. The main objective of this study is to determine experimentally the physical properties of different disaggregated materials from the internal layers of extensive green roofs commonly used in Mediterranean climates. The experimentation presented in this paper allows to calculate the thermal transmittance in steady-state (U-value), the heat storage capacity (Cp), and the dynamic thermal response under a daily thermal oscillation. This work was partially funded by the Spanish government (ENE2015-64117-C5-1-R (MINECO/FEDER) and ULLE10-4E-1305), in collaboration with the company Buresinnova S.A (C/Roc Boronat 117-125, baixos 08018 Barcelona). Moreover, the research leading to these results has received funding from the European Union's Seventh Framework Programme (FP7/2007-2013) under grant agreement n° PIRSES-GA-2013-610692 (INNOSTORAGE) and from European Union’s Horizon 2020 research and innovation programme under grant agreement N° 657466 (INPATH-TES). The authors would like to thank the Catalan Government for the quality accreditation given to their research group (2014 SGR 123). Alvaro de Gracia would like to thank Ministerio de Economia y Competitividad de España for Grant Juan de la Cierva, FJCI-2014-19940. Finally, Julià Coma wants to thank the Departament d'Universitats, Recerca i Societat de la Informació de la Generalitat de;1; Catalunya for his research fellowship.

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    Energy and Buildings
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    Repositori Obert UdL
    Article . 2017
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      Energy and Buildings
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      Repositori Obert UdL
      Article . 2017
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    Authors: Anabel Palacios; Alvaro de Gracia; Laia Haurie; Luisa F. Cabeza; +2 Authors

    The implementation of organic phase change materials (PCMs) in several applications such as heating and cooling or building comfort is an important target in thermal energy storage (TES). However, one of the major drawbacks of organic PCMs implementation is flammability. The addition of flame retardants to PCMs or shape-stabilized PCMs is one of the approaches to address this problem and improve their final deployment in the building material sector. In this study, the most common organic PCM, Paraffin RT-21, and fatty acids mixtures of capric acid (CA), myristic acid (MA), and palmitic acid (PA) in bulk, were tested to improve their fire reaction. Several flame retardants, such as ammonium phosphate, melamine phosphate, hydromagnesite, magnesium hydroxide, and aluminum hydroxide, were tested. The properties of the improved PCM with flame retardants were characterized by thermogravimetric analyses (TGA), the dripping test, and differential scanning calorimetry (DSC). The results for the dripping test show that fire retardancy was considerably enhanced by the addition of hydromagnesite (50 wt %) and magnesium hydroxide (50 wt %) in fatty acids mixtures. This will help the final implementation of these enhanced PCMs in building sector. The influence of the addition of flame retardants on the melting enthalpy and temperatures of PCMs has been evaluated. Peer Reviewed

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    Recolector de Ciencia Abierta, RECOLECTA
    Other literature type . Article . 2018 . Peer-reviewed
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    Repositori Obert UdL
    Article . 2018
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      Other literature type . Article . 2018 . Peer-reviewed
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    Authors: PISELLO, ANNA LAURA; FABIANI, CLAUDIA; MAKAREMI, NASTARAN; CASTALDO, VERONICA LUCIA; +4 Authors

    There is considerable interest recently in by-products for application in green buildings. These materials are widely used as building envelope insulators or blocks. In this study, an experimental study was conducted to test stranded driftwood residues as raw material for possible thermo-acoustic insulation panel and environmentally sustainable brick. The thermal and acoustic characteristics of such a natural by-product were examined. Part of samples were mineralized by means of cement-based additive to reinforce the material and enhance its durability as well as fire resistance. Several mixtures with different sizes of ground wood chips and different quantities of cement were investigated. The thermo-acoustic in-lab characterization was aimed at investigating the thermal conductivity, thermal diffusivity, volumetric specific heat, and acoustic transmission loss. All samples were tested before and after mineralization. Results from this study indicate that it is possible to use stranded driftwood residues as building materials with competitive thermo-acoustic properties. In fact, the thermal conductivity was shown to be always around 0.07 W/mK in the unbound samples, and around double that value for the mineralized samples, which present a much higher volumetric specific heat (1.6 MJ/m3K) and transmission loss capability. The lignin powder showed a sort of intermediate behavior between the unbound and the mineralized samples. The authors would like to thank Gabriele Franceschetti and CVR s.r.l. for assisting the mineralization procedure of the samples. Anna Laura Pisello’s acknowledgments are due to the “CIRIAF program for UNESCO” in the framework of the UNESCO Chair “Water Resources Management and Culture”, for supporting her research. The research was founded by the Italian Environmental Ministry with an agreement entitled “Recovery and energy valorization of stranded driftwood residues” in 2014–2016. The research team leading to these results has received funding from the European Union’s Horizon 2020 research and innovation programme under grant agreement No. 657466 (INPATH–TES) and No. 678407 (ZERO-PLUS).

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    Authors: Pau Gallart-Sirvent; Marc Martín; Gemma Villorbina; Mercè Balcells; +4 Authors

    GREA and DBA are certified agents TECNIO in the category of technology developers from the Government of Catalonia. We thanks to Subproductos Cárnicos Echevarria y Asociados S.L (Cervera, Spain) for supplying the non-edible fat. Moreover, the research leading to these results has received funding from the European Commission Seventh Framework Programme (FP/2007–2013) under grant agreement no. PIRSES-GA-2013-610692 (INNOSTORAGE) and from the European Union's Horizon 2020 research and innovation program under grant agreement no. 657466 (INPATH-TES). The authors would like to thank the Catalan Government for the quality accreditation given to their research groups GREA (2014 SGR 123), Agricultural Biotechnology Research Group (2014 SGR 1296) and DIOPMA (2014 SGR 1543). This work has been partially funded by the Spanish government (CTQ2015-70982-C3-1-R (MINECO/FEDER), ENE2015-64117-C5-1-R (MINECO/FEDER) and ENE2015-64117-C5-2-R (MINECO/FEDER)). Dr Camila Barreneche would like to thank Ministerio de Economia y Competitividad de España for her grant Juan de la Cierva FJCI-2014-22886. Aran Solé would like to thank Ministerio de Economía y Competitividad de España for Grant Juan de la Cierva, FJCI-2015-25741. A set of compounds from non-edible fat waste was prepared and their thermal behavior was studied. The fat was hydrolyzed and crystallized in a simple and robust process to yield palmitic acid-stearic acid (PA-SA) mixtures. The PA-SA mass ratios determined by GC-FID (gas chromatography-flame ionization detection) were similar to those reported for eutectic mixtures of PCMs (phase change materials). DSC (differential scanning calorimetry) results indicated that the melting and solidification temperatures were around 55 °C and 52 °C and the latent heat of the crystallized fractions measured was around 180 kJ kg−1. The thermal cycling reliability of the eutectic mixtures was also tested during 1000 melting/freezing cycles. The loss in melting and solidification enthalpies was below 14% in all mixtures showing a promising behavior for PCM applications. Additionally, the unsaturated fatty acids were recovered and transformed to threo-9,10-dihydroxystearic acid (DHSA) and some of their inorganic salts, which were analyzed by FT-IR (Fourier transform-infrared spectroscopy) and tested for the first time using the DSC technique.

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    Authors: Rathgeber, Christoph; Schmit, Henri; Miró, Laia; Cabeza, Luisa F.; +3 Authors

    The work of ZAE Bayern was part of the project EnFoVerM and was supported by the German Federal Ministry for Economic Affairs and Energy under the project code 0327851D. The work at the University of Lleida is partially funded by the Spanish government (ENE2011-22722, ENE2015-64117-C5-1-R (MINECO/FEDER) and ULLE10-4E-1305). The authors would like to thank the Catalan Government for the quality accreditation given to their research group GREA (2014 SGR 123). GREA is a certified agent TECNIO in the category of technology developers from the Government of Catalonia. The research leading to these results has received funding from the European Union's Seventh Framework Programme (FP7/2007-2013) under grant agreement n° PIRSES-GA-2013-610692 (INNOSTORAGE) and from the European Union’s Horizon 2020 research and innovation programme under grant agreement No 657466 (INPATH-TES). The authors want also to thank the collaboration of Antoni Gil from Massachusetts Institute of Technology (USA), Eduard Oró from Catalonia Institute for Energy Research (Spain), and Jaume Gasia and Gerard Peiró from University of Lleida (Spain). Laia Miró would like to thank the Spanish Government for her research fellowship (BES-2012-051861). The work of the University of Antofagasta was supported by FONDAP SERC-Chile (grant N° 15110019), and the Education Ministry of Chile Grant PMI ANT 1201. Authors thank the SALMAG Company for providing of bischofite. Andrea Gutierrez would like to acknowledge to the Ministry of Education of Chile her doctorate scholarship ANT 1106 and CONICYT/PAI N° 7813110010. Phase change materials (PCM) can provide high thermal energy storage capacities in narrow temperature ranges around their phase change temperature. The expectable maximum storage capacity of a PCM in a defined temperature range is equal to the enthalpy change in that range and can be determined via calorimetric measurements such as differential scanning calorimetry (DSC) or T-History calorimetry. T-History samples (aprox. 15 ml) are about 1000 times larger than DSC samples (aprox. 15 ml). Experiments in a pilot plant are performed to study the charging and discharging behaviour of even larger amounts of the PCM (aprox. 150 l). The common practise is to investigate PCM at one scale, rarely at two scales. In this work, the characterisation was carried out at three scales (DSC, T-History, and pilot plant) for four PCM (RT58, bischofite, D-mannitol, and hydroquinone). Thereby, the question arises how the enthalpy changes measured at different scales and under different conditions can be compared. In literature, the melting enthalpy is usually assigned to a single temperature without indicating the temperature range considered for evaluation. In very few instances, the enthalpy change within a defined temperature range is stated. In both cases, results measured under different conditions are difficult to compare. In this work, it is demonstrated that enthalpy-temperature plots facilitate the comparison and interpretation of measurements obtained under different experimental methods at different sample scales.

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    Journal of Energy Storage
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      Journal of Energy Storage
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      License: CC BY NC ND
      Data sources: UnpayWall
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      Repositori Obert UdL
      Article . 2018
      License: CC BY NC ND
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      Journal of Energy Storage
      Other literature type . Article . 2018 . Peer-reviewed
      License: Elsevier TDM
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